Reactivity of polynuclear zinc-thiolate sites
نویسندگان
چکیده
منابع مشابه
Reactivity of polynuclear zinc-thiolate sites
The proton affinities of a series of monoand polynuclear zinc-thiolate compounds, mimicking zing finger protein and metallothioneins sites, have been investigated by Density Functional Theory calculations. This allows to evaluate the intrinsic nucleophilicity of synthetic and natural zinc-bound thiolates and to compare their relative reactivities. The site specificity of the experimental thiola...
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ژورنال
عنوان ژورنال: International Journal of Quantum Chemistry
سال: 2010
ISSN: 0020-7608
DOI: 10.1002/qua.22866